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GRAPPLE ZINC PRIMER
Heavy Duty Anticorrosion Coating for Steel Structures:
1. Disadvantage of conventional anticorrosion engineering of paint system

Zinc Rich Paint (ZRP) is one of the representative cathodic anticorrosion technologies. It indicates that metal zinc in coated film is eluted in a sacrificial manner when subjected to corrosion as is the case with zinc coated steel and thereby electrons are transferred to steel material to stablize it.


However, in the high corrosion environment such as coastal areas, there is the fault that durability comes to have a short by flying particles of sea salt so that consumption of the zinc becomes intense.

It is often observed that the heavy-duty anticorrosion effect by use of Zinc Rich Paint is ineffective in the three major corrosion regions of Okinawa Prefecture, Kashima in Ibaragi Prefecture and Tomakomai in Hokkaido.


3. Cathodic photo-protection

In the needle-shaped conductive titanium oxide with UV rays from sunlight received, electrons are generated. By transfer of these electrons to metal, the electric potential (corrosion) of the metal itself shifts to "less noble potential" (anticorrosion). Even if there is salt, no rust will be formed on the metal.
It is so-called "Cathodic photo-protection" to prevent metal from rust formation by the light.

2. Development of Grapple Zinc Primer

We developed photocatalyst-containing zinc rich paint (Grapple Zinc Primer), which is produced by adding a special photocatalyst to conventional organic zinc rich paint.





4. Anticorrosion theory of Grapple Zinc Primer

Grapple Zinc Primer allows for long term functioning of superior anticorrosion property even in a severe corrosion environment by electrons obtained through light energy conversion from needle-shaped conductive titanium oxide with UV rays from sunlight received, in addition to high anticorrosion property of zinc in Zinc Rich Paint.



5. Grapple heavy-duty coating system
Coating Process Paint Name Material System Standard Usage
(g/m2/use)
Standard Film
Thickness

(μm/use)
Primer Grapple Zinc Primer Photocatalyst-Containing Organic Zinc Rich Paint 750 75
Under Coating Grapple Under Coating Permeable Modified Epoxy Resin Under Coat (Weak Solvent Type) 510 100
Top Coating Grapple Top Coating HBU (Thick-Film Type Polyurethane Resin Top Coat (Weak Solvent Type) 220 55
Grapple Top Coat HBF Thick-Film Type Fluorine Resin Top Coat (Weak Solvent Type)


Top Coat:
Selectable according to environment conditions
6. Accelerating Test

Ultraviolet Irradiation Combined Cycle Test: Compliant with JIS K 5621



Conventional Material   Development Material
Organic Zinc Rich Paint   Grapple Zinc Primer
Conventional Material Okinawa Environment
(approximate 6 year
equivalent)
Development Material

Our development material has the effect of corrosion inhibition.



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